Monday, December 23, 2013

Morpholine is an organic chemical compound which have the chemical formula O(CH2CH2)2NH. This heterocycle, features both amine and ether functional groups. Because of the amine, morpholine is a base; its conjugate acid is called morpholinium. For example, neutralizing morpholine with hydrochloric acid makes the salt morpholinium chloride.


Rubber Chemicals

A  major  use  of  morpholine  is  as  an  intermediate  in  the  production  of delayed-action  type  rubber  accelerators.  Accelerators  are  added  to  rubber before  fabrication  to  increase  the  rate  of  vulcanization. Morpholine-based delayed-action accelerators are usually made by reacting morpholine with 2-mercaptobenzothiazole.  Several other morpholine-based accelerators have been reported in the literature.

Corrosion Inhibitors

Morpholine is widely used as a neutralizing amine in combating carbonic acid corrosion in condensate return lines of steam boiler systems. The morpholine volatilizes with the steam from the boiler and condenses when the steam does, thereby affording protection to the lines, which otherwise would be subjected to corrosion by the carbonic acid present in the steam condensate. Morpholine vapors protect silver and other metals against corrosion and tarnish by acid fumes, such as sulfur dioxide and hydrogen sulfide.

Morpholine is a component of a corrosion inhibitor system that prevents decomposition of a chlorinated hydrocarbon in a composition containing the chlorinated hydrocarbon and a large amount of water. Corrosion of metal aerosol containers and valves can be prevented by the use of low levels of morpholine.


Morpholine has been employed as a catalyst for the condensation of aldehydes and ketones which contain active methyl or methylene groups. The condensates may be hydrogenated to polyhydroxy compounds which can be sulfated to form surface-active agents. Morpholine has also been used as a gelling agent in the preparation of alumina catalysts for the treatment of hydrocarbons. Catalysts of fine particle size suitable for fluidized solid techniques result from this procedure.

Separating Agents

The physical and chemical properties of morpholine make it useful in various purification procedures. Marked differences in the solubility of the methyl amines in morpholine have led to a convenient extractive method for separating these volatile amines. The addition of morpholine to styrene-containing hydrocarbon mixtures makes possible the isolation of substantially pure styrene by azeotropic distillation. Morpholine is the preferred amine to use in an oil-amine mixture for scrubbing organic sulfur compounds from fuel gas. Morpholine is also used in the purification of acetylene and certain olefins.

Optical Brighteners

Morpholine is an important intermediate in the manufacture of optical brighteners. Optical brighteners are employed by the soap and detergent industry in the compounding of detergents. The diaminostilbene triazine type brightener with morpholine as a substituent on one of the triazine rings is particularly effective on cellulosics. Having greater stability to chlorine bleaches than other types of brighteners, they are particularly suitable for home laundry detergents.

Emulsion polymerization agent

Small  quantities  of  morpholine  are  used  in  the  emulsion  polymerization  of monomers, such as butadiene and isoprene, as well as their copolymerization with styrene, acrylonitrile, and the like.

Polymerisation inhibitor

Morpholine  has  been  used  as  a  temperature  sensitive polymerization inhibitor.  Small  amounts  permit  complete  impregnation  of  porous  materials with  molten  vinylpyrroletype  monomers  just  above  their  melting  points,  but still allow complete polymerization at slightly higher temperatures.


Three methods of producing morpholine have been described:

a)  Reductive ammonation of diethylene glycol and hydrogen. Possible  catalysts  include  copper,  nickel,  cobalt,  chromium,molybdenum, manganese,  platinum,  palladium,  rhodium  and  ruthenium.  Morpholine is recovered by fractional distillation

b)    Dehydration  of  diethanolamine  with  a  strong  acid  such  as  oleum, concentrated  sulfuric  acid  or  concentrated  hydrochloric  acid.The  acid  is neutralized  by  the  addition  of  an  alkali  to  give  the  free  base  of  morpholine. Morpholine  is  recovered  by  extraction  using  an  organic  solvent  or concentrated aqueous alkali followed by distillation .

c.)  Heating  bis(chloroethyl)ether  and  anhydrous  ammonia  in  a  closed vessel.   After venting the  excess  ammonia,  the  product  is  filtered  from ammonium chloride, and purified morpholine obtained by distillation

Import and Export in India

The Import of Morpholine is about 2864 metric tonnes and the Export of Morpholine is about 691 metric tonnes.

Indian producers

Balaji Amines Ltd is the sole producer of morpholine in the country.

The company pioneered the manufacture of Morpholine& Alkyl Morpholines and N-Methyl  Morpholine  Oxide,  which  is  the  preferred  solvent  used  for  the manufacture of viscose staple fibre by the solvent spun process. The company’s range  of  alkyl  morpholines  include  lauryl,  methyl,  ethyl,  hydroxy  ethyl morpholines etc. A  new  plant  of 15000 tonnes  per  annum  capacity  for  manufacturing  GBL,  NMP/ 2P at MIDC, Chincholi, Solapur has been set up.

Global Producers

BASF Germany

Huntsman Corporation

Source: NPCS Team



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Project at a Glance

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  •    Land & Building

            Factory Land & Building

            Site Development Expenses

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             Indigenous Machineries

            Other Machineries (Miscellaneous, Laboratory etc.)

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            Furniture & Fixtures

            Pre-operative and Preliminary Expenses

            Technical Knowhow

            Provision of Contingencies

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           Consumable Store

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            Selling and Distribution Expenses

  •    Salary and Wages

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  •   Share Capital

            Equity Capital

            Preference Share Capital


  •    Annexure 1:: Cost of Project and Means of Finance

  •    Annexure 2::  Profitability and Net Cash Accruals


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  •    Annexure 6 :: Profitability ratios


                Earnings Per Share (EPS)


             Debt Equity Ratio

        Annexure 7   :: Break-Even Analysis

                Variable Cost & Expenses

                Semi-Var./Semi-Fixed Exp.

                Profit Volume Ratio (PVR)

                Fixed Expenses / Cost 


  •   Annexure 8 to 11:: Sensitivity Analysis-Price/Volume

            Resultant N.P.B.T

            Resultant D.S.C.R

   Resultant PV Ratio

   Resultant DER

  Resultant ROI

          Resultant BEP

  •    Annexure 12 :: Shareholding Pattern and Stake Status

        Equity Capital

        Preference Share Capital

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        Determined Capacity P.A of Products/Services

        Achievable Efficiency/Yield % of Products/Services/Items 

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       Expected Sales/ Revenue/ Income of Products/ Services/ Items   

  •    Annexure 14 :: Product wise domestic Sales Realisation

  •    Annexure 15 :: Total Raw Material Cost

  •    Annexure 16 :: Raw Material Cost per unit

  •    Annexure 17 :: Total Lab & ETP Chemical Cost

  •    Annexure 18  :: Consumables, Store etc.,

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  •    Annexure 20  :: Packing Material Cost Per Unit

  •    Annexure 21 :: Employees Expenses

  •    Annexure 22 :: Fuel Expenses

  •    Annexure 23 :: Power/Electricity Expenses

  •    Annexure 24 :: Royalty & Other Charges

  •    Annexure 25 :: Repairs & Maintenance Exp.

  •    Annexure 26 :: Other Mfg. Expenses

  •    Annexure 27 :: Administration Expenses

  •    Annexure 28 :: Selling Expenses

  •    Annexure 29 :: Depreciation Charges – as per Books (Total)

  •   Annexure 30   :: Depreciation Charges – as per Books (P & M)

  •   Annexure 31   :: Depreciation Charges - As per IT Act WDV (Total)

  •   Annexure 32   :: Depreciation Charges - As per IT Act WDV (P & M)

  •   Annexure 33   :: Interest and Repayment - Term Loans

  •   Annexure 34   :: Tax on Profits

  •   Annexure 35   ::Projected Pay-Back Period And IRR